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1Magnesium-mediatedintramolecularreductivecoupling:AstereoselectivesynthesisofC2-symmetric3,4-bis-silyl-substitutedadipicacidderivativesPintuK.
KunduandSunilK.
Ghosh*Bio-OrganicDivision,BhabhaAtomicResearchCentreTrombay,Mumbai400085,IndiaE-mail:ghsunil@barc.
gov.
inTableofContentsEntryDescriptionPage1Figure-S1.
1HNMRSpectrumof2a32Figure-S2.
13CNMRSpectrumof2a43Figure-S3.
1HNMRSpectrumoftrans-1a54Figure-S4.
13CNMRSpectrumoftrans-1a65Figure-S5.
1HNMRSpectrumofcis-1a76Figure-S6.
13CNMRSpectrumofcis-1a87Figure-S7.
1HNMRSpectrumof5a98Figure-S8.
13CNMRSpectrumof5a109Figure-S9.
1HNMRSpectrumof9a1110Figure-S10.
1HNMRSpectrumof13a1211Figure-S11.
13CNMRSpectrumof11a1312Figure-S12.
1HNMRSpectrumof11b1413Figure-S13.
13CNMRSpectrumof11b1514Figure-S14.
1HNMRSpectrumof10a1615Figure-S15.
13CNMRSpectrumof10a1716Figure-S16.
1HNMRSpectrumof13a1817Figure-S17.
13CNMRSpectrumof13a1918Figure-S18.
1HNMRSpectrumoftrans-14a2019Figure-S19.
13CNMRSpectrumoftrans-14a2120Figure-S20.
1HNMRSpectrumoftrans-15a2221Figure-S21.
13CNMRSpectrumoftrans-15a2322Figure-S22.
1HNMRSpectrumofcis-14a2423Figure-S23.
13CNMRSpectrumofcis-14a2524Figure-S24.
1HNMRSpectrumof10b2625Figure-S25.
13CNMRSpectrumof10b2726Figure-S26.
1HNMRSpectrumof13b2827Figure-S27.
13CNMRSpectrumof13b2928Figure-S28.
1HNMRSpectrumoftrans-15b30229Figure-S29.
13CNMRSpectrumoftrans-15b3130Figure-S30.
1HNMRSpectrumof10c3231Figure-S31.
13CNMRSpectrumof10c3332Figure-S32.
1HNMRSpectrumof13c3433Figure-S33.
13CNMRSpectrumof13c3534Figure-S34.
1HNMRSpectrumoftrans-14c3635Figure-S35.
1HNMRSpectrumoftrans-15c3736Figure-S36.
13CNMRSpectrumoftrans-15c3837Figure-S37.
1HNMRSpectrumof(-)-163938Figure-S38.
13CNMRSpectrumof(-)-164039Figure-S39.
Viewofcrystalsof(a)trans-14a;(b)trans-15a413Figure-S1.
1HNMRof2aOSiSiCO2MeCO2MeMeMeMeMe4Figure-S2.
13CNMRof2aOSiSiCO2MeCO2MeMeMeMeMe5Figure-S3.
1HNMRoftrans-1aOSiSiCO2MeCO2MeMeMeMeMe6Figure-S4.
13CNMRoftrans-1aOSiSiCO2MeCO2MeMeMeMeMe7Figure-S5.
1HNMRofcis-1aOSiSiCO2MeCO2MeMeMeMeMe8Figure-S6.
13CNMRofcis-1aOSiSiCO2MeCO2MeMeMeMeMe9Figure-S7.
1HNMRof5aOSiSiCO2MeCO2MeMeMeMeMe10Figure-S8.
13CNMRof5aOSiSiCO2MeCO2MeMeMeMeMe11Figure-S9.
1HNMRof9aTolMe2SiTolMe2SiCO2MeCO2Me12Figure-S10.
1HNMRof11aPhMe2SiCO2H13Figure-S11.
13CNMRof11aPhMe2SiCO2H14Figure-S12.
1HNMRof11bTolMe2SiCO2H15Figure-S13.
13CNMRof11bTolMe2SiCO2H16Figure-S14.
1HNMRof10aPhMe2SiONOO17Figure-S15.
13CNMRof10aPhMe2SiONOO18Figure-S16.
1HNMRof13aSiONOOSiONOOOMeMeMeMe19Figure-S17.
13CNMRof13aSiONOOSiONOOOMeMeMeMe20Figure-S18.
1HNMRoftrans-14aOSiSiOONNOOOOMeMeMeMe21Figure-S19.
13CNMRoftrans-14aOSiSiOONNOOOOMeMeMeMe22Figure-S20.
1HNMRoftrans-15aOSiSiOONNOOOOMeMeMeMe23Figure-S21.
13CNMRoftrans-15aOSiSiOONNOOOOMeMeMeMe24Figure-S22.
1HNMRofcis-14aOSiSiOONNOOOOMeMeMeMe25Figure-S23.
13CNMRofcis-14aOSiSiOONNOOOOMeMeMeMe26Figure-S24.
1HNMRof10bTolMe2SiONOOPhPh27Figure-S25.
13CNMRof10bTolMe2SiONOOPhPh28Figure-S26.
1HNMRof13bSiONOOSiONOOOMeMeMeMePhPhPhPh29Figure-S27.
13CNMRof13bSiONOOSiONOOOMeMeMeMePhPhPhPh30Figure-S28.
1HNMRoftrans-15bOSiSiOONNOOOOMeMeMeMePhPhPhPh31Figure-S29.
13CNMRoftrans-15bOSiSiOONNOOOOMeMeMeMePhPhPhPh32Figure-S30.
1HNMRof10cTolMe2SiONOOArArAr=2-MeO-5-Me-C6H333Figure-S31.
13CNMRof10cTolMe2SiONOOArArAr=2-MeO-5-Me-C6H334Figure-S32.
1HNMRof13cSiONOOSiONOOOMeMeMeMeArArArArAr=2-MeO-5-Me-C6H335Figure-S33.
13CNMRof13cSiONOOSiONOOOMeMeMeMeArArArArAr=2-MeO-5-Me-C6H336Figure-S34.
1HNMRoftrans-14cOSiSiOONNOOOOMeMeMeMeArArArArAr=2-MeO-5-Me-C6H337Figure-S35.
1HNMRoftrans-15cOSiSiOONNOOOOMeMeMeMeArArArArAr=2-MeO-5-Me-C6H338Figure-S36.
13CNMRoftrans-15cOSiSiOONNOOOOMeMeMeMeArArArArAr=2-MeO-5-Me-C6H339Figure-S37.
1HNMRof(-)-16OOOOHH40Figure-S38.
13CNMRof(-)-16OOOOHH41Figure-S39.
Viewofcrystalsof(a)trans-14a;(b)trans-15a(a)trans-14a(b)trans-15a