中中tatanano

SAFETYDATASHEETDatePrepared:07/20/2015MSDSNo:SilicaProductsDate-Revised:04/18/2017RevisionNo:2SILICAPRODUCTS1.
PRODUCTANDCOMPANYIDENTIFICATIONMATERIAL:SILICAPRODUCTSGENERALUSE:RefractoryinsulationMANUFACTURERAlliedMineralProducts,Inc.
2700SciotoParkwayColumbus,OH43221Telephone:(614)-876-0244E-MailofpersonresponsibleforSDS:sdsinfo@alliedmin.
comAlliedMineralProductsEuropeB.
V.
Energieweg54691SETholen,NetherlandsTelephone:+31-166601200AlliedRefractoryProductsIndiaPvt.
Ltd.
SM-5Bol,G.
I.
D.
C.
b/hTataNano,Tal.
:SanandDist.
:Ahmedabad,Gujarat3821705,IndiaTelephone:+91-2717-616800合联联联天天天天天天天天天天天天天天术术号2天天,中中,300459EmergencyContact:黄黄卫Telephone:+86-22-25210378AlliedMineralProductsSouthAfrica(Pty)Ltd.
CrockerRoadWadevilleExt.
4WadevilleExt.
4Germinston,1407SouthAfricaTelephone:+27-11-902-6930FabricadosnoBrasilparaAlliedMineralProducts,Inc.
DeTogniS/AMateriaisRefratariosTelephone:+55-35-2101-2222FabricadoenChileparaAlliedMineralProducts,Inc.
PorRefractariosIungeLtda.
Telephone:(56-2)2745-36132.
HAZARDSIDENTIFICATIONGHSCLASSIFICATIONSHealth:TargetOrganToxicity(Repeatedexposure),Category2GHSLABELHealthhazardSIGNALWORD:WARNINGHAZARDSTATEMENTSH373:Maycausedamagetoorgans(stateallorgansaffected,ifknown)throughprolongedorrepeatedexposure(statePage1of9SAFETYDATASHEETDatePrepared:07/20/2015MSDSNo:SilicaProductsDate-Revised:04/18/2017RevisionNo:2SILICAPRODUCTSrouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard).
PRECAUTIONARYSTATEMENT(S)Prevention:P260:Donotbreathedust/fume/gas/mist/vapours/spray.
P285:Incaseofinadequateventilationwearrespiratoryprotection.
P501:Disposeofcontents/containerto.
.
.
EMERGENCYOVERVIEWIMMEDIATECONCERNS:NotApplicablePOTENTIALHEALTHEFFECTSEYES:Causeseyeirritation.
SKIN:Maycauseskinirritation.
INGESTION:Notalikelyrouteofentry.
INHALATION:Donotbreathedustasitmaycausepermanentlunginjury(Silicosis).
TheIARChasclassifiedcrystallinesilicainhaledintheformofquartzorcristobalitecarcinogenictohumans(GroupI).
USGHSCarcinogenClassification:WARNINGCarcinogen,Category1H350:MayCauseCancer(Inhalation)MEDICALCONDITIONSAGGRAVATED:Theconditionofindividualswithlungdisease(e.
g.
,bronchitis,emphysema,chronicobstructivepulmonarydisease)canbeaggravatedbyexposure.
ROUTESOFENTRY:InhalationTARGETORGANSTATEMENT:Respiratorysystem,skinCOMMENTS:Crystallinesilicaexistsinseveralforms,themostcommonofwhichisquartz.
Ifcrystallinesilica(quartz)isheatedtomorethan870oC(1600oF)itcanchangetoaformofcrystallinesilicaknownastrydimite,andifcrystallinesilica(quartz)isheatedtomorethan1470oC(2680oF),itcanchangetoaformofcrystallinesilicaknownascristobalite.
Crystallinesilicaastrydimiteandcristobalitearemorefibrogenicthancrystallinesilicaasquartz.
3.
COMPOSITION/INFORMATIONONINGREDIENTSChemicalNameWt.
%CASSilica,Crystallinequartz(non-respirable)Upto10014808-60-7Silica,Crystallinequartz(respirablefraction)<1014808-60-7Page2of9SAFETYDATASHEETDatePrepared:07/20/2015MSDSNo:SilicaProductsDate-Revised:04/18/2017RevisionNo:2SILICAPRODUCTS4.
FIRSTAIDMEASURESEYES:Immediatelyflusheyeswithplentyofwaterforatleast15minutes.
Seekmedicalattentionifirritationpersists.
SKIN:Washwithsoapandwater.
Seekmedicalattentionifirritationdevelopsorpersists.
INGESTION:Drinkplentyofwater.
Consultaphysician.
INHALATION:Removetofreshair.
Ifnotbreathing,giveartificialrespirationorgiveoxygenbytrainedpersonnel.
Seekimmediatemedicalattention.
SIGNSANDSYMPTOMSOFOVEREXPOSUREEYES:Irritation,burning,redness,pain.
SKIN:Contactmaycauseskinirritation.
INGESTION:Notalikelyrouteofentry.
INHALATION:Mayincludeshortnessofbreath,wheezing,coughing,andsputumproduction.
ACUTEEFFECTS:Overexposuretodustmayaggravaterespiratoryconditions.
CHRONICEFFECTS:Prolongedorrepeatedoverexposuremaycauselungdamage.
NOTESTOPHYSICIAN:NotApplicable5.
FIREFIGHTINGMEASURESGENERALHAZARD:Thisproductisnoncombustibleandwillnotigniteorcontributetotheintensityofafire.
EXTINGUISHINGMEDIA:Asappropriateforsurroundingfire.
FIREFIGHTINGPROCEDURES:Asappropriateforsurroundingfire.
FIREFIGHTINGEQUIPMENT:Asinanyfire,wearself-containedbreathingapparatuspressure-demandandfullprotectivegear.
6.
ACCIDENTALRELEASEMEASURESSMALLSPILL:Vacuumorsweepupmaterialandplaceinadisposalcontainer.
Avoiddustgeneration.
LARGESPILL:Cleanupusingmethodswhichavoiddustgeneration.
Compressedairshouldnotbeusedtocleanupspills.
Wearappropriatepersonalprotectiveequipment.
Collectmaterialinacompatibleandappropriatelylabeledcontainer.
Disposeofmaterialfromprocessing,installation,maintenance,ortear-outoperationsinaccordancewithapplicableregulations.
ENVIRONMENTALPRECAUTIONSWATERSPILL:Dustsofas-manufacturedrefractoryproducthavealoworderofaquatictoxicity,areinsoluble,andarenotverymobile.
Baseduponthisinformation,itisnotbelievedtobeasignificantthreattotheenvironmentifaccidentallyreleasedintowater.
LANDSPILL:Dustsofas-manufacturedrefractoryproductarenotbelievedtobeasignificantthreattotheenvironmentifaccidentallyreleasedonland.
Dustandmaterialgeneratedduringmaintenanceandtear-outoperationsmaybecontaminatedwithotherhazardoussubstances(e.
g.
,metals,alkalinematerials).
Evaluationofdustandmaterialfromspecificprocessesshouldbeperformedtodetermineifanenvironmentalthreatexistsinthecaseofarelease.
Page3of9SAFETYDATASHEETDatePrepared:07/20/2015MSDSNo:SilicaProductsDate-Revised:04/18/2017RevisionNo:2SILICAPRODUCTSAIRSPILL:Exhaustventilationisrecommendedtomaintainairbornedustconcentrationsbelowregulatoryexposurelevels.
Consultindividualoperatingpermitsforallowableairemissions.
GENERALPROCEDURES:NotApplicableSPECIALPROTECTIVEEQUIPMENT:PersonalProtectiveEquipmentshouldbewornasindicatedinSection8.
7.
HANDLINGANDSTORAGEGENERALPROCEDURES:Keepdryandavoidexposuretomoisturepriortouse.
HANDLING:Useproperproceduresforinstallationandoperation.
Contactmanufacturerforproperprocedures.
Practicegoodhousekeepingtominimizedustgeneration.
Respiratorsshouldbewornduringinstallationandremovalofproductifdustcouldbegenerated.
ConsultSection8forrespiratorselectioninformation.
STORAGE:Storeinadryarea.
STORAGETEMPERATURE:NotApplicable8.
EXPOSURECONTROLS/PERSONALPROTECTIONEXPOSUREGUIDELINESOSHAHAZARDOUSCOMPONENTS(29CFR1910.
1200)EXPOSURELIMITSChemicalNameTypeppmmg/m3Silica,Crystallinequartz(non-respirable)OSHAPELTWA[1]0.
1[1]ACGIHTLVTWA[2]0.
025[2]SupplierOELTWANAOSHATABLECOMMENTS:1.
OSHAhasissuedaproposedsilicastandardloweringthePELto0.
05mg/m3forsilica,crystallinequartz-respirablefraction.
TheproposedstandardmaintainsthePELforcristobaliteat0.
05mg/m3.
2.
Silicaexposurelimitslistedareforrespirablefractions.
ENGINEERINGCONTROLS:Localexhaustventilationmaybenecessarytocontrolanyaircontaminantstowithintheirexposurelimitsduringtheuseofthisproduct.
PERSONALPROTECTIVEEQUIPMENTEYESANDFACE:Wearsafetyglasseswithsideshields(orgoggles)andafaceshield.
SKIN:Userubbergloves.
Washthoroughlyafterhandling.
RESPIRATORY:Ifitisnotpossibletoreduceairborneexposurelevelstobelowtheexposurelimitswithventilation,usethetablebelowtoassistyouinselectingrespiratorsthatwillreducepersonalexposurestobelowtheexposurelimits.
Theassignedprotectionfactor(APF)istheminimumanticipatedlevelofprotectionprovidedbyeachtypeofrespiratorworninaccordancewithanadequaterespiratoryprotectionprogram.
Forexample,anAPFof10meansthatthePage4of9SAFETYDATASHEETDatePrepared:07/20/2015MSDSNo:SilicaProductsDate-Revised:04/18/2017RevisionNo:2SILICAPRODUCTSrespiratorshouldreducetheairborneconcentrationofaparticulatebyafactorof10,sothatiftheworkplaceconcentrationofaparticulatewas150ug/m3,thenarespiratorwithanAPFof10shouldreducetheconcentrationofparticulateto15ug/m3.
AssignedProtectionFactorTypeofRespirator10Anyair-purifyingelastomerichalf-maskrespiratorequippedwithappropriatetypeofparticulatefilter.
Appropriatefilteringfacepiecerespirator.
Anyair-purifyingfullfacepiecerespiratorequippedwithappropriatetypeofparticulatefilter.
Anynegativepressure(demand)supplied-airrespiratorequippedwithahalf-mask.
25Anypoweredair-purifyingrespiratorequippedwithahoodorhelmetandahighefficiency(HEPA)filter.
Anycontinuousflowsupplied-airrespiratorequippedwithahoodorhelmet.
50Anyair-purifyingfullfacepiecerespiratorequippedwithN-100,R-100,orP-100filter(s).
Anypoweredair-purifyingrespiratorequippedwithatight-fittingfacepiece(halforfullfacepiece)andahigh-efficiencyfilter.
Anynegativepressure(demand)supplied-airrespiratorequippedwithafullfacepiece.
Anycontinuousflowsupplied-airrespiratorequippedwithatight-fittingfacepiece(halforfullfacepiece).
Anynegativepressure(demand)self-containedrespiratorequippedwithafullfacepiece.
1000Anypressure-demandsupplied-airrespiratorequippedwithahalf-mask.
PROTECTIVECLOTHING:Wearclothingwhichminimizesskincontactorexposure.
WORKHYGIENICPRACTICES:Usegoodpersonalhygienewhenhandlingthisproduct.
Washhandsafteruse,beforesmoking,orbeforeusingthetoilet.
OTHERUSEPRECAUTIONS:RecommendchestX-raysandyearlyvitalcapacitytestsforemployeesregularlyexposedtosilicaforearlydetectionofsilicosis.
Complywithallguidelinesforcrystallinesilicaexposure.
9.
PHYSICALANDCHEMICALPROPERTIESPHYSICALSTATE:GranularsolidODOR:NoOdorAPPEARANCE:Granulartofinematerial.
pH:NotApplicablePERCENTVOLATILE:NotApplicableFLASHPOINTANDMETHOD:NotApplicableFLAMMABLELIMITS:NotApplicableVAPORPRESSURE:NotApplicablePage5of9SAFETYDATASHEETDatePrepared:07/20/2015MSDSNo:SilicaProductsDate-Revised:04/18/2017RevisionNo:2SILICAPRODUCTSVAPORDENSITY:NotApplicableBOILINGPOINT:NotApplicableFREEZINGPOINT:NotApplicableMELTINGPOINT:Referenceproductliterature.
SOLUBILITYINWATER:<3%EVAPORATIONRATE:NotApplicableSPECIFICGRAVITY:2to3.
000g/cc10.
STABILITYANDREACTIVITYHAZARDOUSPOLYMERIZATION:Hazardouspolymerizationwillnotoccur.
STABILITY:Stable.
CONDITIONSTOAVOID:NotApplicableHAZARDOUSDECOMPOSITIONPRODUCTS:NotApplicableINCOMPATIBLEMATERIALS:Strongacids,bases,oxidizingagents.
11.
TOXICOLOGICALINFORMATIONACUTETOXICITYNOTES:Acutesilicosiscanoccurwithexposurestoveryhighconcentrationsofrespirablecrystallinesilicaoveraveryshorttimeperiod.
USGHSCarcinogenClassificationIARC:TheInternationalAgencyforResearchonCancer("IARC")concludedthattherewas"sufficientevidenceinhumansforthecarcinogenicityofcrystallinesilicaintheformsofquartzorcristobalitefromoccupationalsources",andthatthereis"sufficientevidenceinexperimentalanimalsforthecarcinogenicityofquartzandcristobalite".
TheoverallIARCevaluationwasthat"crystallinesilicainhaledintheformofquartzorcristobalitefromoccupationalsourcesiscarcinogenictohumans(GroupI)".
TheIARCevaluationnotedthat"carcinogenicitywasnotdetectedinallindustrialcircumstancestudies.
Carcinogenicitymaybedependentoninherentcharacteristicsofthecrystallinesilicaoronexternalfactorsaffectingitsbiologicalactivityordistributionofitspolymorphs".
ForfurtherinformationontheIARCevaluation,seeIARCMonographsontheEvaluationofCarcinogenicRiskstoHumans,Volume68,"Silica,SomeSilicates.
.
.
"(1997).
(Emphasisadded).
NTP:CrystallineSilica(respirable)-NTPreportsmayreasonablybeanticipatedtobeacarcinogen.
OSHA:Crystallinesilica(quartz)isnotregulatedbytheU.
S.
OccupationalSafetyandHealthAdministrationasacarcinogen.
Thereissubstantialliteratureontheissuesofthecarcinogenicityofcrystallinesilica,whichthereadershouldconsultforadditionalinformation.
Asummaryoftheliteratureissetforthin"Exposuretocrystallinesilicaandriskoflungcancer;theepidemiologicalevidence",Thorax,Volume51,pp.
97-102(1996).
TheofficialstatementoftheAmericanThoracicSocietyontheissueofsilicacarcinogenicitywaspublishedin"AdverseEffectsofCrystallineSilicaExposure",AmericanJournalofRespiratoryandCriticalCareMedicine,Volume155,pp.
761-765(1997).
Theofficialstatementconcludedthat"Theavailabledatasupporttheconclusionthatsilicosisproducesincreasedriskforbronchogeniccarcinoma.
Thecancerriskmayalsobeincreasedbysmokingandothercarcinogensintheworkplace.
Page6of9SAFETYDATASHEETDatePrepared:07/20/2015MSDSNo:SilicaProductsDate-Revised:04/18/2017RevisionNo:2SILICAPRODUCTSEpidemiologicstudiesprovideconvincingevidenceforincreasedcancerriskamongtobaccosmokerswithsilicosis.
Forworkerswithsilicosis,therisksforlungcancerarerelativelyhighandconsistentamongvariouscountriesandinvestigators.
Silicosisshouldbeconsideredaconditionthatpredisposesworkerstoanincreasedriskoflungcancer".
Id.
at763.
STOT-SINGLEEXPOSURE:SILICOSIS-causedbytheinhalationandretentionofrespirablecrystallinesilicadust.
Silicosiscanexistinseveralforms,chronic(orordinary),andaccelerated(oracute).
ChronicorOrdinarySilicosisisthemostcommonformofsilicosis,andcanoccuraftermanyyearsofexposuretorelativelylowlevelsofairbornerespirablecrystallinesilicadust.
Itisfurtherdefinedaseithersimpleorcomplicatedsilicosis.
SimpleSilicosisischaracterizedbylunglesions(shownasradiographicopacities)lessthan1centimeterindiameter,primarilyintheupperlungzones.
Often,simplesilicosisisnotassociatedwithsymptoms,detectablechangesinlungfunction,ordisability.
Simplesilicosismaybeprogressiveandmaydevelopintocomplicatedsilicosisorprogressivemassivefibrosis(PMF).
ComplicatedSilicosisorPMFischaracterizedbylunglesions(shownasradiographicopacities)greaterthan1centimeterindiameter.
AlthoughtheremaybenosymptomsassociatedwithcomplicatedsilicosisorPMF,thesymptoms,ifpresent,areshortnessofbreath,wheezing,cough,andsputumproduction.
12.
ECOLOGICALINFORMATIONECOTOXICOLOGICALINFORMATION:NoneKnownBIOACCUMULATION/ACCUMULATION:NotApplicableDISTRIBUTION:NotApplicableCHEMICALFATEINFORMATION:NotApplicableGENERALCOMMENTS:Dustsofas-manufacturedrefractoryproducthavealoworderofaquatictoxicity,areinsoluble,andarenotverymobile.
Baseduponthisinformation,itisnotbelievedtobeasignificantthreattotheenvironmentifaccidentallyreleasedonlandorintowater.
However,dustandmaterialgeneratedduringmaintenanceandtear-outoperationsmaybecontaminatedwithotherhazardoussubstances(e.
g.
,metals,respirablecrystallinesilica,alkalinematerials).
Evaluationofdustandmaterialfromspecificprocessesshouldbeperformedtodetermineifanenvironmentalthreatexistsinthecaseofrelease.
13.
DISPOSALCONSIDERATIONSPRODUCTDISPOSAL:Theas-manufacturedrefractoryproductorrefractorydustisnotconsideredahazardouswaste.
Dustandmaterialgeneratedduringuse,maintenanceandtear-outoperationsmaybecontaminatedwithotherhazardoussubstances(e.
g.
,metals,alkalinematerials)fromaparticularapplication.
Additionally,thespentrefractorycouldcontainreactionproductsnotoriginallypresentinthesuppliedrefractorymaterial.
Contaminantsorreactionproductshavethepotentialtocausetherefractorywastetoexhibithazardouswastecharacteristics.
Itistheresponsibilityoftheusertoconsultapplicableregulationspriortodisposalofanyindustrialproducttoensurewastedisposalcompliance.
Wasteanalysisandcharacterizationmaybenecessarytodetermineproperwastedisposal.
WasteManagement:Dustscouldcontainrespiratoryhazards.
Topreventwastematerialsbecomingairborneduringwastegeneration,storage,transportation,anddisposal,properdustcontrolmeasuresarerecommended.
14.
TRANSPORTINFORMATIONDOT(DEPARTMENTOFTRANSPORTATION)PROPERSHIPPINGNAME:NotRegulatedPage7of9SAFETYDATASHEETDatePrepared:07/20/2015MSDSNo:SilicaProductsDate-Revised:04/18/2017RevisionNo:2SILICAPRODUCTSROADANDRAIL(ADR/RID)PROPERSHIPPINGNAME:NotRegulatedforTransportUNNUMBER:N/APACKINGGROUP:N/ASPECIALPROVISIONS:NotApplicableAIR(ICAO/IATA)SHIPPINGNAME:NotRegulatedPRIMARYHAZARDCLASS/DIVISION:NotApplicableVESSEL(IMO/IMDG)SHIPPINGNAME:NotRegulatedMARINEPOLLUTANT#1:NotApplicable15.
REGULATORYINFORMATIONUNITEDSTATESTSCA(TOXICSUBSTANCECONTROLACT)TSCASTATUS:AllingredientsinthismixtureareincompliancewithTSCA.
CALIFORNIAPROPOSITION65:WARNING:Thisproductcontainscrystallinesilica,achemicalknowntotheStateofCaliforniatocausecancer.
RCRASTATUS:NotregulatedCANADAWHMIS(WORKPLACEHAZARDOUSMATERIALSINFORMATIONSYSTEM):ThisproductisaWHMIScontrolledsubstance.
16.
OTHERINFORMATIONDate-Revised:04/18/2017REVISIONSUMMARY:ThisMSDSreplacesthe04/18/2017MSDS.
HMISRATINGHEALTH*2FLAMMABILITY0PHYSICALHAZARD0PERSONALPROTECTIONNFPACODES020DISCLAIMER:Allinformationprovidedhereisbasedondatabelievedtobereliable.
However,THEINFORMATIONANDTHEPRODUCTAREPROVIDEDWITHOUTANYREPRESENTATIONORWARRANTY,EXPRESSORIMPLIED,INCLUDINGBUTNOTLIMITEDTOREPRESENTATIONSANDWARRANTIESREGARDINGPage8of9SAFETYDATASHEETDatePrepared:07/20/2015MSDSNo:SilicaProductsDate-Revised:04/18/2017RevisionNo:2SILICAPRODUCTSACCURACYORCORRECTNESS,THEEFFECTSOFUSINGTHEPRODUCT,THERESULTSTOBEOBTAINED,FITNESSFORAPARTICULARPURPOSE,ORTHESAFETYORTOXICITYOFTHEPRODUCT.
Itistheusers'responsibilitytodeterminethesafety,toxicity,andsuitabilityfortheiruseoftheproductandtocomplywithallapplicablestatutesandregulations.
Theconditionsormethodsofhandling,storage,use,anddisposaloftheproductarebeyondourcontrol.
Forthisandotherreasons,AlliedMineralProducts,Inc.
doesnotassumeresponsibilityandexpresslydisclaimsliabilityforloss,damage,orexpensearisingoutof,relatingto,orinanywayconnectedwiththehandling,storage,use,ordisposalofthisproduct.
ThisSDSisnotintendedasalicensetooperateunder,orarecommendationtoinfringeon,anypatents.
Appropriatewarningsandsafehandlinginstructionsshouldbeprovidedtohandlersandusers.
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