SECTION1:Identificationofthesubstance/preparationandofthecompany/undertaking1.
1.
ProductidentifierTradename:LGHB2OtherInformation:ForChemicalEmergencySpill,Leak,Fire,Exposure,orAccidentCallCHEMTRECDayorNightWithinUSAandCanada:1-800-424-93001703-527-3887(collectcallsaccepted)Location:CHEMTREC2900FairviewParkDriveFallsChurchVA22042-4513USA1.
2.
RelevantidentifiedusesofthesubstanceormixtureandusesadvisedagainstRecommendeduses:Lubricant1.
3.
DetailsofthesupplierofthesafetydatasheetSupplierCompany:SKFMAINTENANCEPRODUCTSAddress:P.
O.
Box2350Zipcode:3430DTCity:NieuwegeinCountry:NETHERLANDSE-mail:sebastien.
david@skf.
comPhone:+31306307200Homepage:www.
skf.
com1.
4.
EmergencyTelephoneNumber+31306307200SECTION2:Hazardsidentification2.
1.
ClassificationofthesubstanceormixtureHazComclassification:Eyeirritation,Category2A;H319Mostseriousharmfuleffects:Causesseriouseyeirritation.
IndividualswithaknownallergytoBenzenesulfonicacid,mono-C16-24-alkylderivs.
,calciumsalts,Sulfonicacids,petroleum,calciumsalts,Benzenesulfonicacid,C10-16-alkylderivs.
,calciumsalts,C14-16-18AlkylPhenolmayexhibitanallergicresponsetotheproduct.
2.
2.
LabelelementsPictogramsLGHB2SafetyDataSheet1/10LGHB2SafetyDataSheetSignalword:WarningContainsSubstance:Benzenesulfonicacid,C10-13-alkylderivs.
,calciumsaltsH-phrasesCausesseriouseyeirritation.
P-phrasesWeareyeprotection/faceprotection.
2.
3.
OtherhazardsNoneknown.
SECTION3:Composition/informationoningredients3.
2.
MixturesSubstanceCASNoConcentrationNotesBenzenesulfonicacid,C10-16-alkylderivs.
,calciumsalts68584-23-65-notuseajetofwater,asitmayspreadthefire.
5.
2.
SpecialhazardsarisingfromthesubstanceormixtureNotflammable,butcombustible.
Theproductdecomposeswhencombustedandthefollowingtoxicgasescanbeformed:Carbonmonoxideandcarbondioxide/Sulphuroxides/Nitrousgases/Aldehydes.
5.
3.
Adviceforfire-fightersWearSelf-ContainedBreathingApparatus(SCBA)withachemicalprotectionsuitonlywherepersonal(close)contactislikely.
Movecontainersfromdangerareaifitcanbedonewithoutrisk.
Avoidinhalationofvaporandsmokegases-seekfreshair.
SECTION6:Accidentalreleasemeasures6.
1.
Personalprecautions,protectiveequipmentandemergencyproceduresFornon-emergencypersonnel:Stayupwind/keepdistancefromsource.
Wearsafetygoggles/faceprotection.
Weargloves.
Incaseofinsufficientventilation,wearrespiratoryprotectiveequipment.
Foremergencyresponders:Inadditiontotheabove:Protectivesuitisrecommended.
6.
2.
EnvironmentalprecautionsPreventspillagefromenteringdrainsand/orsurfacewater.
6.
3.
MethodsandmaterialforcontainmentandcleaningupSweepup/collectspillsforpossiblereuseortransfertosuitablewastecontainers.
Wipeupminorspillswithadampcloth.
6.
4.
ReferencetoothersectionsSeesection8fortypeofprotectiveequipment.
Seesection13forinstructionsondisposal.
SECTION7:Handlingandstorage7.
1.
PrecautionsforsafehandlingUsetheproductunderwell-ventilatedconditions.
Runningwaterandeyewashequipmentshouldbeavailable.
Washhandsbeforebreaks,beforeusingrestroomfacilities,andattheendofwork.
7.
2.
Conditionsforsafestorage,includinganyincompatibilities3/10LGHB2SafetyDataSheetStoresafely,outofreachofchildrenandawayfromfood,animalfeedingstuffs,drugs,etc.
Keepintightlyclosedoriginalpackaging.
Donotstorewiththefollowing:Strongoxidisers.
Storeinadryarea.
7.
3.
Specificenduse(s)None.
SECTION8:Exposurecontrols/personalprotection8.
1.
ControlparametersOccupationalexposurelimitSubstancenameTimeperiodppmmg/m3fiber/cm3CommentsRemarksOilmistOSHA5Oilmist,mineraloilOilmistACGIHTWA5Pure,highlyandseverelyrefinedA4,IA4=NotClassifiableasaHumanCarcinogen.
I=Inhalablefraktion.
Measuringmethods:Compliancewithoccupationalexposurelimitsmaybecheckedbyoccupationalhygienemeasurements.
Legalbasis:ACGIHThresholdLimitValues(TLV's)andBiologicalExposureIndices(BEI's),2019.
OSHA29CFRpart1910.
1000,tableZ1-Z3,LimitsforAirContaminants2006.
8.
2.
ExposurecontrolsAppropriateengineeringcontrols:Wearthepersonalprotectiveequipmentspecifiedbelow.
Personalprotectiveequipment,eye/faceprotection:Wearsafetygoggles.
Personalprotectiveequipment,handprotection:Intheeventofdirectskincontact,wearprotectivegloves:Typeofmaterial:Nitrilerubber.
Breakthroughtimehasnotbeendeterminedfortheproduct.
Changeglovesoften.
Thesuitabilityanddurabilityofagloveisdependantonusage,e.
g.
frequencyanddurationofcontact,glovematerialthickness,functionalityandchemicalresistance.
Alwaysseekadvicefromtheglovesupplier.
Personalprotectiveequipment,respiratoryprotection:Notrequired.
Incaseofinsufficientventilation,wearrespiratoryprotectiveequipment.
Filtertype:A.
P.
Environmentalexposurecontrols:Ensurecompliancewithlocalregulationsforemissions.
SECTION9:Physicalandchemicalproperties9.
1.
InformationonbasicphysicalandchemicalpropertiesParameterValue/unitStateSolidsubstanceColourLightbrownOdourCharacteristicSolubilityInsolubleinthefollowing:Water.
ExplosivepropertiesNon-explosive4/10LGHB2SafetyDataSheetOxidisingpropertiesNon-oxidising.
ParameterValue/unitRemarkspH(solutionforuse)NodatapH(concentrate)NodataMeltingpointNodataFreezingpointNodataInitialboilingpointandboilingrangeNodataFlashPointNodataEvaporationrateNodataFlammability(solid,gas)NodataFlammabilitylimitsNodataExplosionlimitsNodataVapourpressureNodataVapourdensityNodataRelativedensity0.
900(68°F)Partitioncoefficientn-octonol/waterNodataAuto-ignitiontemperatureNodataDecompositiontemperatureNodataViscosityNodataOdourthresholdNodata9.
2OtherinformationParameterValue/unitRemarksDensity900kg/m3(68°F)SECTION10:Stabilityandreactivity10.
1.
ReactivityReactswiththefollowing:Strongoxidisers.
10.
2.
ChemicalstabilityTheproductisstablewhenusedinaccordancewiththesupplier'sdirections.
10.
3.
PossibilityofhazardousreactionsNoneknown.
10.
4.
ConditionstoavoidAvoidcontactwithmoistureandwater.
10.
5.
IncompatiblematerialsStrongoxidisers.
10.
6.
HazardousdecompositionproductsTheproductdecomposeswhencombustedorheatedtohightemperaturesandthefollowingtoxicgasescanbeformed:Carbonmonoxideandcarbondioxide/Sulphuroxides/Nitrousgases/Aldehydes.
5/10LGHB2SafetyDataSheetSECTION11:Toxicologicalinformation11.
1.
InformationontoxicologicaleffectsAcutetoxicity-oralBenzenesulfonicacid,C10-16-alkylderivs.
,calciumsalts,cas-no68584-23-6OrganismTestTypeExposuretimeValueConclusionTestmethodSourceRatLD50>5000mg/kgOECD401Benzenesulfonicacid,mono-C16-24-alkylderivs.
,calciumsalts,cas-no70024-69-0OrganismTestTypeExposuretimeValueConclusionTestmethodSourceRatLD50>5000mg/kgOECD401Sulfonicacids,petroleum,calciumsalts,cas-no61789-86-4OrganismTestTypeExposuretimeValueConclusionTestmethodSourceRatLD50>16000mg/kgbwBenzenesulfonicacid,C10-13-alkylderivs.
,calciumsalts,cas-no-OrganismTestTypeExposuretimeValueConclusionTestmethodSourceRatLD504445mg/kgbwC14-16-18AlkylPhenol,cas-no-OrganismTestTypeExposuretimeValueConclusionTestmethodSourceRatLD502000mg/kgbwIngestionmaycausediscomfort.
Theproductdoesnothavetobeclassified.
Basedonexistingdata,theclassificationcriteriaaredeemednottohavebeenmet.
Acutetoxicity-dermalBenzenesulfonicacid,C10-16-alkylderivs.
,calciumsalts,cas-no68584-23-6OrganismTestTypeExposuretimeValueConclusionTestmethodSourceRabbitLD50>5000mg/kgbwOECD402Benzenesulfonicacid,mono-C16-24-alkylderivs.
,calciumsalts,cas-no70024-69-0OrganismTestTypeExposuretimeValueConclusionTestmethodSourceRabbitLD50>5000mg/kgOECD402Sulfonicacids,petroleum,calciumsalts,cas-no61789-86-4OrganismTestTypeExposuretimeValueConclusionTestmethodSourceRabbitLD50>4000mg/kgBenzenesulfonicacid,C10-13-alkylderivs.
,calciumsalts,cas-no-OrganismTestTypeExposuretimeValueConclusionTestmethodSourceRatLD502000mg/kgbwC14-16-18AlkylPhenol,cas-no-OrganismTestTypeExposuretimeValueConclusionTestmethodSourceRatLD502000mg/kgbwTheproductdoesnothavetobeclassified.
Basedonexistingdata,theclassificationcriteriaaredeemednottohavebeenmet.
Acutetoxicity-inhalationLGHB2OrganismTestTypeExposuretimeValueConclusionTestmethodSourceATE(Dust/Mist)137.
20mg/lSulfonicacids,petroleum,calciumsalts,cas-no61789-86-46/10LGHB2SafetyDataSheetOrganismTestTypeExposuretimeValueConclusionTestmethodSourceRatLC50(aerosol)4h>1.
9mg/lTheproductdoesnothavetobeclassified.
Basedonexistingdata,theclassificationcriteriaaredeemednottohavebeenmet.
Skincorrosion/irritation:Mayirritatetheskin-maycausereddening.
Theproductdoesnothavetobeclassified.
Testdataarenotavailable.
Seriouseyedamage/eyeirritation:Irritatingtoeyes.
Causesaburningsensationandtearing.
Respiratorysensitisationorskinsensitisation:Accordingtotests,theproductneednotbeclassified.
TheproductcontainssmallamountsofBenzenesulfonicacid,mono-C16-24-alkylderivs.
,calciumsalts,Sulfonicacids,petroleum,calciumsalts,Benzenesulfonicacid,C10-16-alkylderivs.
,calciumsalts,C14-16-18AlkylPhenol.
Individualswithaknownallergymayexhibitanallergicresponsetotheproduct.
Germcellmutagenicity:Theproductdoesnothavetobeclassified.
Testdataarenotavailable.
Carcinogenicproperties:Theproductdoesnothavetobeclassified.
Testdataarenotavailable.
ThisproductdoesnotcontainanycarcinogensorpotentialcarcinogensatreportablequantitiesaslistedbyOSHA,IARCorNTP.
Reproductivetoxicity:Theproductdoesnothavetobeclassified.
Testdataarenotavailable.
SingleSTOTexposure:Inhalationofdustmaycauseirritationtotheupperairways.
Theproductdoesnothavetobeclassified.
Testdataarenotavailable.
RepeatedSTOTexposure:Theproductdoesnothavetobeclassified.
Testdataarenotavailable.
Aspirationhazard:Theproductdoesnothavetobeclassified.
Testdataarenotavailable.
Othertoxicologicaleffects:Noneknown.
SECTION12:Ecologicalinformation12.
1.
ToxicityBenzenesulfonicacid,C10-16-alkylderivs.
,calciumsalts,cas-no68584-23-6OrganismSpeciesExposuretimeTestTypeValueConclusionTestmethodSourceAlgaePseudokirchneriellasubcapitata72hEL50>1000mg/lCrustaceaDaphniamagna48hEL50>1000mg/lFishCyprinodonvariegatus96hLL50>1000mg/lOECD203Benzenesulfonicacid,mono-C16-24-alkylderivs.
,calciumsalts,cas-no70024-69-0OrganismSpeciesExposuretimeTestTypeValueConclusionTestmethodSourceAlgaePseudokirchneriellasubcapitata72hEC50>1000mg/lCrustaceaDaphniamagna48hEC50>1000mg/lFishCyprinodonvariegatus96hLL50>10000mg/lOECD2037/10LGHB2SafetyDataSheetSulfonicacids,petroleum,calciumsalts,cas-no61789-86-4OrganismSpeciesExposuretimeTestTypeValueConclusionTestmethodSourceAlgaePseudokirchneriellasubcapitata72hEC50>1000mg/lCrustaceaDaphniamagna48hEC50>1000mg/lOECD202FishCyprinodonvariegatus96hLC50>10000mg/lOECD203Benzenesulfonicacid,C10-13-alkylderivs.
,calciumsalts,cas-no-OrganismSpeciesExposuretimeTestTypeValueConclusionTestmethodSourceAlgaeNameofspeciesnotspecified96hNOEC500μg/lAlgaeNameofspeciesnotspecified96hLOEC1mg/lAlgaePseudokirchneriellasubcapitata96hEC5029mg/lCrustaceaDaphniamagna48hEC502.
9mg/lFishNameofspeciesnotspecified96hLC501-notspecified21dNOEC1.
18mg/lFishNameofspeciesnotspecified72hNOEC0.
23mg/lCrustaceaNameofspeciesnotspecified48hNOEC379μg/lC14-16-18AlkylPhenol,cas-no-OrganismSpeciesExposuretimeTestTypeValueConclusionTestmethodSourceCrustaceaDaphniamagna48hEC50>100mg/lOECD202Theproductcontainssmallquantitiesofenvironmentallyhazardoussubstances.
Theproductdoesnothavetobeclassified.
Basedonexistingdata,theclassificationcriteriaaredeemednottohavebeenmet.
12.
2.
PersistenceanddegradabilityTestdataarenotavailable.
12.
3.
BioaccumulativepotentialTestdataarenotavailable.
12.
4.
MobilityinsoilNotexpectedtobemobileinsoil.
Testdataarenotavailable.
12.
5.
ResultsofPBTandvPvBassessment8/10LGHB2SafetyDataSheetNoassessmenthasbeenmade.
12.
6.
OtheradverseeffectsOilproductsmaycausesoilandwaterpollution.
Germanwaterpollutionclassification(WGK):2SECTION13:Disposalconsiderations13.
1.
WastetreatmentmethodsAvoiddischargetodrainorsurfacewater.
Ifthisproductassuppliedbecomesawaste,itdoesnotmeetthecriteriaofahazardouswasteasdefinedundertheResourceConservationandRecoveryAct(RCRA)40CFR261.
Empty,cleansedpackagingshouldbedisposedofforrecycling.
Uncleansedpackagingistobedisposedofviathelocalwaste-removalscheme.
SECTION14:Transportinformation14.
1.
UN-No.
:Notapplicable.
14.
4.
Packinggroup:Notapplicable.
14.
2.
UNpropershippingname:Notapplicable.
14.
5.
Environmentalhazards:Notapplicable.
14.
3.
Transporthazardclass(es):Notapplicable.
14.
6.
SpecialprecautionsforuserNone.
14.
7.
TransportinbulkaccordingtoAnnexIIofMARPOLandtheIBCCodeNotapplicable.
SECTION15:Regulatoryinformation15.
1.
Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixtureNFPAratingsHealthhazard:2Flammability:1Instability:015.
2.
ChemicalSafetyAssessmentOtherInformation:Chemicalsafetyassessmenthasnotbeenperformed.
SECTION16:OtherinformationVersionhistoryandindicationofchangesVersionRevisiondateResponsibleChanges2.
1.
05/15/2020BureauVeritasHSE/SRU3,8,11-12,15-16Abbreviations:PBT:Persistent,BioaccumulativeandToxicvPvB:VeryPersistentandVeryBioaccumulativeSTOT:SpecificTargetOrganToxicity9/10LGHB2SafetyDataSheetOtherInformation:Thissafetydatasheethasbeenpreparedforandappliestothisproductonly.
Itisbasedonourcurrentknowledgeandtheinformationthatthesupplierwasabletoprovideabouttheproductatthetimeofpreparation.
ThesafetydatasheetcomplieswithapplicablelawonpreparationofsafetydatasheetsinaccordancewithCFR29,§1910.
1200.
Trainingadvice:Athoroughknowledgeofthissafetydatasheetshouldbeaprerequisitecondition.
Revisiondate:5/15/2020Replacesdate:11/2/2018Classificationmethod:Calculationbasedonthehazardsoftheknowncomponents.
Testdata.
Documentlanguage:US10/10
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