ICP-OESandICP-MSDetectionLimitGuidance2007EvansAnalyticalGroup,LLCPrintedinUSA08/07BR0233Li5AtomicNumberSymbolICP-OESSolutionDL(g/L)2.
5ICP-OESSolidDL(ppmwt)29Cu11Na12Mg13Al14Si15P16S17Cl18Ar1H4Be37Rb55Cs42Mo41Nb86Rn74W43Tc75Re44Ru76Os45Rh77Ir46Pd78Pt47Ag79Au48Cd80Hg60Nd62Sm63Eu64Gd65Tb61Pm66Dy67Ho68Er69Tm49In50Sn51Sb52Te53I81Tl82Pb83Bi84Po85At58Ce59Pr70Yb90Th92U93Np94Pu95Am96Cm91Pa97Bk98Cf99Es100Fm101Md102No105107106108109111110112DbSgHsBhMtUunUuu1141163Li10Ne2He9O8F7N6C5B57La89Ac71Lu103Lr87Fr88Ra104Rf72Hf40Zr39Y38Sr56Ba73Ta54Xe19K20Ca21Sc22Ti30Zn31Ga32Ge33As34Se35Br36Kr23V24Cr25Mn26Fe27Co28NiUubUuqUuhPeriod1654327LanthanidesActinidesGroup1IA2IIA3IIIB4IVB5VB6VIB7VIIB9VIII81011IB12IIB13IIIA14IVA15VA16VIA17VIIA18VIIIAToconvertg/Ltoppmwt,usethefollowingcalculation:[solconc(g/L)*prepvol(L)]/samplemass(g)=sampleconcentrationinppmwt(mg/Kg)0.
1gICP-OESsamplemass50mlICP-OESprepvolume1SolutiondilutiontorunonICP-OES500TypicalICP-OESdilutionfactor0.
05gICP-MSsamplemass100mlICP-MSprepvolume1SolutiondilutiontorunonICP-MS2,000TypicalICP-MSdilutionfactorThedetectionlimitsaretheoreticalbestcasescenariosassumingtherearenospectralinterferencesaffectingthebestisotopeorwavelengthforagivenelement.
Foranygivendetermination,theactualmethoddetectionlimitcanbeanorderofmagnitudehigherormore.
Usethisasaguide,notabsoluteinformation0.
005ICP-MSSolutionDL(g/L)0.
01ICP-MSSolidDL(ppmwt)512.
50.
50.
0050.
00050.
010.
001500.
5250.
250.
010.
0010.
020.
0021000.
5500.
250.
050.
0050.
10.
01100.
550.
250.
0010.
0010.
0020.
002400000.
5200000.
250.
00050.
00050.
0010.
0011050.
050.
12020501010250.
001510.
0021025555155555505050502.
52.
52.
52.
50.
52.
52.
52.
52.
52.
5252525250.
0050.
0010.
00050.
00050.
00050.
0020.
00050.
0020.
00050.
0010.
00050.
0040.
0010.
0020.
010.
0020.
0010.
0010.
0010.
0040.
0010.
0040.
0010.
0020.
0010.
0080.
0020.
004555010501005055505050502.
52.
52552550252.
52.
5252525250.
00050.
00050.
0010.
00050.
00050.
00050.
00050.
00050.
00050.
00050.
010.
00050.
0050.
0010.
0010.
0020.
0010.
0010.
0010.
0010.
0010.
0010.
0010.
020.
0010.
0110505050101505050505050100525252550.
5252525252525500.
00050.
0050.
00050.
0010.
00050.
0010.
00050.
00050.
00050.
0010.
0010.
00050.
00050.
0010.
010.
0010.
0020.
0010.
0020.
0010.
0010.
0010.
0020.
0020.
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0015050505010505010101010101025252525525255555550.
00050.
00050.
00050.
00050.
00050.
00050.
00050.
00050.
00050.
00050.
00050.
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00050.
0010.
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0010.
0010.
0010.
0010.
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0010.
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0010.
0010.
00150500252500.
00050.
00050.
0010.
0012007EvansAnalyticalGroup,LLCPrintedinUSA08/07BR023InductivelyCoupledPlasmaSpectroscopyEAGLocationsUnitedStatesArizona903S.
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uk@eaglabs.
comWWW.
EAGLABS.
COMInductivelyCoupledPlasmaSpectroscopytechniquesare"wet"samplingmethodswheresamplesareintroducedinliquidformforanalysis.
Inplasmaemissionspectroscopy(OES),asamplesolutionisintroducedintothecoreofinductivelycoupledargonplasma(ICP),whichgeneratestemperatureofapproximately8000°C.
Atthistemperatureallelementsbecomethermallyexcitedandemitlightattheircharacteristicwavelengths.
Thislightiscollectedbythespectrometerandpassesthroughadiffractiongratingthatservestoresolvethelightintoaspectrumofitsconstituentwavelengths.
Withinthespectrometer,thisdiffractedlightisthencollectedbywave-lengthandampliedtoyieldanintensitymeasurementthatcanbeconvertedtoanelementalconcentrationbycomparisonwithcalibrationstandards.
Inplasmamassspectroscopy(MS),theinductivelycoupledargonplasma(ICP)isonceagainusedasanexcitationsourcefortheelementsofinterest.
HoweverincontrasttoOES,theplasmainICP-MSisusedtogenerateionsthatarethenintroducedtothemassanalyzer.
Theseionsarethenseparatedandcollectedaccordingtotheirmasstochargeratios.
Theconstituentsofanunknownsamplecanthenbeidentiedandmeasured.
ICP-MSoffersextremelyhighsensitivitytoawiderangeofelements.
StrengthsLimitationsUpto70elementscanbedeterminedsimultaneouslyinasinglesampleanalysis.
Theemissionspectraarecomplexandinter-elementinterferencesarepossibleifthewave-lengthoftheelementofinterestisveryclosetothatofanotherelement.
Theusefulworkingrangeisoverseveralordersofmagnitude.
DuringMassSpectrometry,thecommonmatrixelementsandothermolecularspeciescaninterferewiththemeasurementofsomeelements.
Doublychargedormolecularionicspeciescancreatedifcultiesinquantications.
Instrumentationissuitabletoautomation,thusenhancingaccuracy,precisionandthroughput.
Thesampletobeanalyzedmustbedigestedpriortoanalysisinordertodissolvetheelement(s)ofinterest.
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